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If you want to run on two independent skype instances one a single machine, for example one for your personal skype account, and one for your work account, it's very simple.
Create a shortcut to your skype.exe.
Right-click it, select "Shortcut" tab.
Add /secondary to the Target field, if you have installed Skype on the default location, then this would look something like:
"C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary
Click OK to save changes and your are done.
Enjoy your alternative second skype.
Create a shortcut to your skype.exe.
Right-click it, select "Shortcut" tab.
Add /secondary to the Target field, if you have installed Skype on the default location, then this would look something like:
"C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary
Click OK to save changes and your are done.
Enjoy your alternative second skype.